clinker production;clinker;steel slag 3.5%
Steel slag is used for iron correction materials for cement production. Steel slag does not contain carbonate. It can not only replace iron ore when preparing cement clinkers, but also provides calcium, silicon and aluminum, which has a good carbon reduction effect.The main raw materials of the cement are calcium, silica, aluminum and iron materials. Each raw material forms the mineral phase of cement clinker through high temperature solid phase reaction. It can be seen from the chemical components, mineral characteristics, and micro -structures of the steel slag that the steel slag also contains RO, Feo, Fe2O3 and other iron phases, thereby having the conditions to replace iron correction materials. In addition, the steel slag also contains calcium, silicon, aluminum, etc. that can be burned into raw materials such as CAO (most of the content between 40% and 50%)), which can save some calcium, silicon and aluminum raw materials. In view of this steel slag fot iron correctional material technology route. Generally, tthe mineral component of iron correction material for cement is hematite Fe2O3, while the iron phase in steel slag mainly exists in the form of RO, FeO, Fe2O3, Fe, CF and so on. When steel slag is used as raw material, regardless of the form of iron, the iron phase in its high temperature solid phase reaction can provide the iron component to form the C4AF mineral phase required for cement clinker.Combined with the actual production, the target value of WISCO steel slag clinker for transportation to a cement company along the Yangtze River for burning cement clinker is KH=0.91士0.02, SM=2.5士0.1, IM=1.5士0.1. Users of this Life Cycle Assessment data should ensure that the steel slag input parameters reflect realistic proportions and purity levels that match those used in the described process. Attention should be paid to the carbon emission boundaries defined from 'cradle to gate', ensuring that the carbon footprint calculations account for all stages except 'clinker calcination process' which is not included. The functional unit for this data set is 1 ton of P·I type Portland cement. Data users should integrate these LCA results with specific cement production scenarios to ensure accurate application.
As can be seen from Figure 1, the main raw materials of cement are calcium materials, siliceous materials, aluminum materials and iron materials. Each raw material forms the cement material mineral phase through high-temperature solid phase reaction. It can be seen from the chemical composition, mineral properties and microstructure of steel slag that steel slag also contains iron phases such as RO, FeO and Fe;O:, thus having the conditions to replace iron correction materials. In addition, steel slag also contains CaO (mostly between 40% and 50%) and other calcium, silicon, aluminum, etc. required for cement burning raw materials, which can save some calcium, siliceous and aluminum raw materials. In view of this steel slag The technical route for making iron correction materials is shown in Figure 2. As can be seen from Figure 2, the mineral component of iron correction materials for general cement is hematite Fe,O;, while the iron phase in steel slag mainly exists in the form of ROFeOFe;O;, FeCF, etc. When steel slag is used as raw material, no matter what form the iron is present in, the iron phase in the high-temperature solid-state reaction can provide the iron component to form the C.AF mineral phase required for cement clinker.Based on the actual production, taking the steel slag transported by Wuhan Iron and Steel Co., Ltd. to a cement company along the Yangtze River for firing cement clinker as an example, the target values of steel slag clinker are: KH=0.91±0.02, SM=2.5±0.1,IM=1.5±0.1. Its raw material components and clinker production formula are shown in Table 1 and Table 2.